Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
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منابع مشابه
Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol-ecules per asymmetric unit. The central Ni atom of each independent mol-ecule has a nearly perfect tetra-hedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the fir...
متن کاملNitrogen Quadrupole Coupling in the Microwave Ground State Spectra of Tertiary Butyl Isocyanide and Phenyl Isocyanide
Z. Naturforsch. 41 a, 1302-1306 (1986); received August 7, 1986 The microwave ground state spectra of tert.-butyl isocyanide, (CH3)3CNC, and phenyl isocyanide, C6H 5NC, have been measured by microwave Fourier transform spectroscopy in the region 5.0 to 8.0 GHz and analysed for nuclear quadrupole hyperfine splitting due to ‘*N. The nuclear quadrupole coupling constants are shown to be in accorda...
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At pH 7.0, ZOO, both in the absence and presence of phosphates, the time course of n-butyl isocyanide binding to deoxyhemoglobin is biphasic, and the two kinetic phases can be isolated spectrally and identified with the properties of the a and /3 chains. Under all conditions at this pH, both the association and dissociation rate constants of the p chains are at least 10 times larger than the co...
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The binding of n-butyl isocyanide to human hemoglobin has been examined by means of rapid mixing and chemical relaxation kinetics. It is seen that an extended Adair scheme (ADAIR, G. S. (1925) .I. BioZ. Chem. 63, 529) can be applied to describe the kinetic data. Two relaxation processes are observed which are attributed to binding of ligand to the LY and /3 subunits. The effect of temperature o...
متن کاملPalladium-catalyzed chemoselective synthesis of indane-1,3-dione derivatives via tert-butyl isocyanide insertion.
A simple and efficient strategy for the synthesis of indane-1,3-dione derivatives through a palladium(0)-catalyzed reaction incorporating tert-butyl isocyanide has been developed. In addition, by applying this protocol as the key step, indenopyrazole derivatives can be easily synthesized in high yields in a one-pot procedure. This methodology is tolerant of a wide range of substrates and applic...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808020138